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Abstract #4879

Molecular Weight of Sugar Structures impacts Shielding Effect of Gd-Ions in Polysaccharides.

Patrick Werner1,2, Matthias Taupitz2, Sophia Ber3, and Leif Schröder1
1German Cancer-research center (DKFZ), Heidelberg, Germany, 2Charite Berlin, Berlin, Germany, 3Universität Heidelberg, Heidelberg, Germany

Synopsis

Keywords: Contrast Agent, Relaxometry, GBCA, gadolinium, long-term deposition, GAGs, dextran sulfate

Detailed biochemical information on the long-term deposition of Gd3+ in the body after administration of GBCAs is still missing. Glycosaminoglycans should be considered as chelators of released Gd3+. We used dextran-sulfate to study the effect of polysaccharides with different molecular weights on the observable relaxivity. Chelation was observed through an increase in relaxation. Moreover, a molecular weight-specific shielding revealed by subsequent reduced R1 occurs at higher polysaccharide/Gd-ion ratios. This coincided with observations of Gd-induced aggregation. Similar shielding of re-chelated Gd3+can lead to an underestimation of deposited Gd-ions in the body and requires further research.

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