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Abstract #0223

2H imaging of [2,3,3-2H2]serine metabolism

Friederike Hesse1, Jacob Low1, Jianbo Cao1, Flaviu Bulat1, Felix Kreis2, and Kevin Brindle1
1CRUK CI, University of Cambridge, Cambridge, United Kingdom, 2Bayer, Berlin, Germany

Synopsis

Keywords: Deuterium, Deuterium

Motivation: Formate overflow linked to mitochondrial oxidative serine catabolism has been observed in various forms of cancer, and there is evidence that elevated formate concentrations promote cell infiltration.

Goal(s): Our goal was to monitor serine catabolism using deuterium metabolic imaging.

Approach: Cell experiments were conducted using a 14.1 T high-resolution NMR spectrometer and 2H experiments on tumors in vivo using a 7.0 T horizontal bore magnet.

Results: [2,3,3-2H2]serine catabolism can be monitored directly from measurements of 2H-formate production and indirectly from 2H-labeling of water.

Impact: Monitoring [2,3,3-2H2]serine metabolism holds huge potential when assessing novel cancer treatments that target the one-carbon pathway to inhibit tumor cell proliferation.

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Keywords